These are the minimates from the Spider-Man 3 wave, so these guys are meant to represent Toby Maguire & Topher Grace. I don't see the likeness myself, I guess Brock looks a little like Topher, but Maguie... no. Although it's emo Parker from the much mocked "dark Peter" segment of the movie.
I got these guys for half price in order to fulfill the "buy amount x and get free shipping" for a toy order. For that, they're pretty good. I'm not certain if I should be putting Brock in my civilian minimate box or the Villain minimate box. Could go either way.
You know, come to think of it, I don't think either one of them wore these clothes in the movie.